2016年5月10日星期二

Triisopropylsilane

The basic information of Triisopropylsilane
Product Name: Triisopropylsilane
Synonyms:Tris-isopropylsilane;(ME2CH)3SIH;SILANE IP3H;TIS;TIPS;TRIISOPROPYLSILANE;Triisopropylsilane (TIPS);Triisopropylsilane [Cas#
CAS:6485-79-6
MF:C9H22Si
MW:158.36
EINECS:464-880-1

Triisopropylsilane  Chemical Properties
bp :84-86 °C35 mm Hg(lit.)
density :0.773 g/mL at 25 °C(lit.)
refractive index :n20/D 1.434(lit.)
Fp :99 °F
storage temp. :Store at RT.
Sensitive :Moisture Sensitive
BRN :1733718
CAS DataBase Reference:6485-79-6(CAS DataBase Reference)
Chemical Properties:Clear colorless liquid

Usage:The bulky isopropyl groups (vs. ethyl) allow for more selective reductions, e.g., beta-selective reduction of anomeric C-phenyl ketals, but do not diminish their activity (e.g. in the copper triflate catalyzed reductive etherification of trimethylsilyl ethers).

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